Synthesis and Structure of Some Zinc and Cadmium 1,2-Cyclohexanedione Dioximines

被引：2

作者：

Coropceanu, E. ^{[1
,2
]}

Croitor, L. ^{[3
]}

Ciloci, A. ^{[4
]}

Clapco, S. ^{[4
]}

Labliuc, S. ^{[4
]}

Codreanu, S. ^{[2
]}

Fonari, M. ^{[3
]}

机构：

[1] Moldavian Acad Sci, Inst Chem, Kishinev, Moldova

[2] Tiraspol State Univ, Kishinev, Moldova

[3] Moldavian Acad Sci, Inst Appl Phys, Kishinev, Moldova

[4] Moldavian Acad Sci, Inst Microbiol & Biotechnol, Kishinev, Moldova

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2017年 / 43卷 / 07期

关键词：

coordination compounds; crystal structure; d(10)-metals; 1,2-cyclohexanedione dioxime; ONE-DIMENSIONAL ZN(II); LUMINESCENT PROPERTIES; MONONUCLEAR CD(II); CRYSTAL-STRUCTURE; COMPLEXES; LIGAND; COPPER(II); DIOXIMATE; CENTERS;

D O I：

10.1134/S1070328417070053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [Zn(CH3COO)(2)(NioxH(2))(DMF)(H2O)] (I), [Cd(CH3COO)(2)(NioxH(2))(DMF)(H2O)] (II), [Zn(CH3COO)(2)(NioxH(2))(S-Nia)(H2O)] center dot DMF (III), [Zn(CH3COO)(2)(NioxH(2))(Nia)(H2O)] (IV), and [Zn(CH3COO)(2)(NioxH(2))(INia)(H2O)] (V), where NioxH(2) is 1,2-cyclohexanedione dioxime, S-Nia is thionicotinamide, Nia is nicotinamide, and INia is isonicotinamide, were prepared and investigated. Compounds I-III were studied by X-ray diffraction (CCDC nos. 1505280-1505282 for I-III, respectively). Testing of zinc complexes containing various ligands demonstrated that at the optimized concentration (5 mg/L), they can be used for stimulating biosynthesis of both standard (57.14%, pH 4.7) and acid-labile (17.63%, pH 2.5) amylases by the micromycete Aspergillus niger CNMN FD 06 without affecting the duration of producer culturing.

引用

页码：433 / 440

页数：8

共 50 条

[1] Synthesis and structure of some zinc and cadmium 1,2-cyclohexanedione dioximines
E. Coropceanu
L. Croitor
A. Ciloci
S. Clapco
S. Labliuc
S. Codreanu
M. Fonari
Russian Journal of Coordination Chemistry, 2017, 43 : 433 - 440
[2] 1,2-CYCLOHEXANEDIONE
DEBORGER, L
VERZELE, M
LAMMENS, H
ANTEUNIS, M
BULLETIN DES SOCIETES CHIMIQUES BELGES, 1964, 73 (1-2): : 73 - &
[3] STRUCTURE OF PHOTOREACTION PRODUCT OF 1,2-CYCLOHEXANEDIONE .1.
OKADA, J
NAKANO, K
MASAKI, N
IIZUKA, H
TERADA, Y
YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1976, 96 (09): : 1081 - 1084
[4] STRUCTURE OF 1,2-CYCLOHEXANEDIONE PHOTOPRODUCT .2.
OKADA, J
FUJIMOTO, A
NAKANO, K
MASAKI, N
IIZUKA, H
TERADA, Y
CHEMICAL & PHARMACEUTICAL BULLETIN, 1976, 24 (10) : 2406 - 2408
[5] 1,2-CYCLOHEXANEDIONE REACTION WITH AMINES
KOZLOV, NS
KOVALEVA, VN
ZHURNAL ORGANICHESKOI KHIMII, 1973, 9 (11): : 2254 - 2256
[6] THE STRUCTURE OF PHOTOREACTION PRODUCT OF 1,2-CYCLOHEXANEDIONE .3.
OKADA, J
NAKANO, K
KIMURA, M
TERADA, Y
YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN, 1984, 104 (06): : 583 - 586
[7] SYNTHESIS OF ALPHA-HALOADIPIC ACIDS FROM 1,2-CYCLOHEXANEDIONE
STAROSTIN, EK
MAZURCHIK, AA
IGNATENKO, AV
NIKISHIN, GI
SYNTHESIS-STUTTGART, 1992, (10): : 917 - 918
[8] 1,2-CYCLOHEXANEDIONE DIOXIME - A REAGENT FOR NICKEL
VOTER, RC
BANKS, CV
DIEHL, H
ANALYTICAL CHEMISTRY, 1948, 20 (05) : 458 - 460
[9] 1,2-CYCLOHEXANEDIONE DIOXIME - A REAGENT FOR PALLADIUM
VOTER, RC
BANKS, CV
DIEHL, H
ANALYTICAL CHEMISTRY, 1948, 20 (07) : 652 - 654
[10] Michael additions of β-nitrostyrenes to 1,2-cyclohexanedione
Simpkins, Chad
Hunt, David A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243

← 1 2 3 4 5 →