A method to control structural transformations of manganese(III,IV) oxides

被引：0
|
作者：
Vol'khin, VV [1 ]
Leont'eva, GV [1 ]
Bakhireva, OI [1 ]
机构：
[1] Perm State Tech Univ, Perm 614600, Russia
来源：
INORGANIC MATERIALS | 1998年 / 34卷 / 06期
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D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
(M = H+, Li+, Na+, K+, Ca2+, Sr2+, Ba2+; 0 < x < 4; 2.96 < y < 3.40; n less than or equal to 6.30), a method is proposed to control structural transformations of manganese(III, IV) oxides by introducing M+ or M2+ modifier ions. Depending on the size of the ion and its ability to retain surrounding water molecules, different structures can be obtained upon heat treatment: psilomelane, cryptomelane, pyrolusite, and spinel.
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页码：574 / 577
页数：4
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