Intercalation Reactions of Layered Manganese(III,IV) Oxides

被引：8
|
作者：
Ammundsen, Brett [1 ]
Wortham, Etienne [1 ]
Jones, Deborah J. [1 ]
Roziere, Jacques [1 ]
机构：
[1] Univ Montpellier 2, CNRS, Lab Agregats Mol & Mat Inorgan, ESA 5072, F-34095 Montpellier 5, France
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1998年 / 311卷
关键词：
manganese oxide; birnessite; alkylammonium intercalates; polyaniline; nanocomposite electrode materials;
D O I：
10.1080/10587259808042406
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Layered hydrated birnessite-type manganese oxides have been intercalated with n-alkylammonium ions by ion-exchange for interlayer sodium or potassium, and by acid-base reactions. The expanded phases have modified interlayer environments and can be used as precursors for intercalation of aniline, which is oxidised and polymerised between the layers.
引用
收藏
页码：327 / 332
页数：6
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