4,4′-Bipyridine-1,1′-diium 2,3,5,6-tetrabromoterephthalate dihydrate

被引：5

作者：

Kumagai, Hitoshi ^{[1
]}

Kawata, Satoshi ^{[2
]}

机构：

[1] Inst Mol Sci, Aichi, Japan

[2] Fukuoka Univ, Dept Chem, Fukuoka 8140180, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

日本学术振兴会;

关键词：

data-to-parameter ratio = 17.2; mean σ(C-C) = 0.005 Å; R factor = 0.031; single-crystal X-ray study; T = 293 K; wR factor = 0.086;

D O I：

10.1107/S1600536811035926

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C10H10N22+center dot C8Br4O42-center dot 2H(2)O, consists of a tetrabromoterephthalate dianion, a 4,4'-bipyridinium dication and two solvent water molecules. Crystallographic inversion centers are situated at the center of the aromatic ring of the dianion as well as at the midpoint of the carbon-carbon bond connecting the pyridine rings in the dication. In the crystal, intermolecular N-H center dot center dot center dot O hydrogen-bonding interactions between tetrabromoterephthalate dianions and protonated 4,4'-bipyridinium dications result in the formation of a chain-like structure. Further O-H center dot center dot center dot O hydrogen bonds between carboxylate O atoms and water molecules lead to the formation of a two-dimensional network in the crystal structure.

引用

页码：O2636 / +

页数：9

共 50 条

[11] THERMAL CLEAVAGE OF 1,1]-DIACETYL-1,1],4,4]-TETRAHYDRO-4,4]-BIPYRIDINE
NIELSEN, AT
MAZUR, JH
MOORE, DW
BERRY, KH
JOURNAL OF ORGANIC CHEMISTRY, 1964, 29 (10): : 2898 - &
[12] Crystal Structure of 1,1′-dimethyl-[4,4′-bipyridine]-1,1′-diium tetrachloridozincate(II), C12H14Cl4N2Zn
Song, Qingmei
Song, Lijun
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2017, 232 (03): : 461 - 462
[13] 4,4'-Dimethyl-2,2'-bipyridine 1,1'-Dioxide
Kanno, H
Iijima, K
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 498 - 499
[14] 4,4′-Bipyridine-3,3′-dicarboxylic acid dihydrate
Bond, AD
Feeder, N
Redman, JE
Sanders, JKM
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : o869 - o871
[15] Crystal structure of [tris(4,4 '-bipyridine)]diium bis(1,1,3,3-tetracyano-2-ethoxypropenide) trihydrate
Setifi, Fatima
Valkonen, Arto
Setifi, Zouaoui
Nummelin, Sami
Touzani, Rachid
Glidewell, Christopher
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1246 - +
[16] Interpenetrating supramolecular lattices in 4,4′-bipyridine-2,3,5,6-tetrahydroxy-1,4-benzoquinone (3/2)
Cowan, JA
Howard, JAK
Leech, MA
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 : 1196 - 1198
[17] 2,2",3,3",4,4",5,5"-Octaphenyl-1,1′:4′,1"-terphenyl and 2′,3′,5′,6′-tetrafluoro-2,2",3,3",4,4",5,5"-octaphenyl-1,1′:4′,1"-terphenyl
Budy, Stephen M.
Nichol, Gary S.
Loy, Douglas A.
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2012, 68 : O23 - O27
[18] The twinned crystal structure of [4,4′-bipyridine]-1,1′-diium hexachloridostannate(IV), C10H10N2SnCl6
Reiss, Guido J.
van Megen, Martin
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2022, 237 (02): : 281 - 284
[19] 4,4′-Bipyridine-2,3,4,5,6-pentafluorobenzoic acid (1/2)
Zhang, Xiangdong
Wang, Lijuan
Ge, Chunhua
Men, Yanmei
Zhang, Rui
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2438 - O2438
[20] Multiple N-H•••NC, C-H•••NC and nitrile•••π interactions in 4,4′-bipyridine-1,1′-diium bis(1,1,3,3-tetracyano-2-ethoxypropenide): structure determination and DFT calculations of anion•••π cation interaction energies
Setifi, Fatima
Geiger, David K.
Razak, Ibrahim Abdul
Setifi, Zouaoui
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2015, 71 : 658 - +

← 1 2 3 4 5 →