4,4'-Dimethyl-2,2'-bipyridine 1,1'-Dioxide

被引:3
|
作者
Kanno, H
Iijima, K
机构
[1] Department of Chemistry, Faculty of Science, Shizuoka University, Shizuoka 422
关键词
D O I
10.1107/S010827019601548X
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
There are four molecules in a unit cell of the title compound, C12H12N2O2, and the structure of only half a molecule has been determined because of its twofold rotational symmetry. The dihedral angle between the two pyridine rings is 61.3 degrees and the non-bonded distance between O atoms in the N-oxide groups is 2.96 Angstrom A. The skew conformation of the skeleton is almost the same as that of the tetrakis(2,2'-bipyridine 1,1'-dioxide)-lanthanum(III) complex.
引用
收藏
页码:498 / 499
页数:2
相关论文
共 50 条
  • [1] Isomerization and racemization of (acetylacetonato)bis(4,4′-dimethyl-2,2′-bipyridine 1,1′-dioxide)chromium(III), (acetylacetonato)bis(4,4′-dimethoxy-2,2′-bipyridine 1,1′-dioxide)chromium(III) and (acetylacetonato)bis(4,4′-diethoxy-2,2′-bipyridine 1,1′-dioxide)chromium(III) complexes
    Kanno, H
    Yagi, M
    Utsuno, S
    Fujita, J
    [J]. INORGANICA CHIMICA ACTA, 1998, 281 (02) : 221 - 224
  • [2] Solubilities of 2,2'-bipyridine and 4,4'-dimethyl-2,2'-bipyridine in supercritical carbon dioxide
    Bai, Yu
    Yang, Hai-Jian
    Quan, Can
    Guo, Cun-Yue
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (05): : 2074 - 2076
  • [3] (E,E)-4,4'-dimethyl-2,2'-(1,1'-dibenzyl-azino)diphenol
    Chang, Jian-Guo
    Li, Ji-Kun
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4061 - U3155
  • [4] Synthesis of 4,4′-dimethyl-2,2′-bipyridine catalyzed by Pd/C
    Wu, XH
    Yang, ZC
    Qin, W
    Jiang, ZH
    [J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2006, 26 (02) : 260 - 262
  • [5] 4,4′-dimethyl-2,2′-[1,1′-(ethane-1,2-diyldinitrilo)diethylidyne]diphenol
    Chakkaravarthi, G.
    Anthonysamy, A.
    Balasubramanian, S.
    Manivannan, V.
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4475 - U4903
  • [6] Trichloro(4,4′-dimethyl-2,2′-bipyridine-N,N′)manganese(III) acetonitrile solvate(1/1)
    Abboud, KA
    Ward, BH
    Talham, DR
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 180 - 181
  • [7] cis-dibrornobis(4,4′-dimethyl-2,2′-bipyridine)manganese(II)
    Sakamoto, J
    Yoshikawa, N
    Takashima, H
    Tsukahara, K
    Kanehisa, N
    Kai, Y
    Matsumura, K
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : M352 - M353
  • [8] Crystal chemistry of the 4,4′-dimethyl-2,2′bipyridine/copper bromide system
    Willett, RD
    Pon, G
    Nagy, C
    [J]. INORGANIC CHEMISTRY, 2001, 40 (17) : 4342 - 4352
  • [9] (4,4′-dimethyl-2,2′-bipyridine)(ethynylbenzene)(triphenylphosphine)platinum(II) hexafluoroantimonate
    Wu, MM
    Zhang, LY
    Qin, YH
    Chen, ZN
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M210 - M211
  • [10] Synthesis, characterization and crystal structure of 6-Chloro-4,4′-dimethyl-2,2′-bipyridine and 4,4′-Dimethyl 2,2′-bipyridine N-Oxide
    Conterosito, Eleonora
    Magistris, Claudio
    Barolo, Claudia
    Croce, Gianluca
    Milanesio, Marco
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2016, 1107 : 337 - 343