Synthesis and spectroscopic properties of a series of metal-free and metallo-phthalocyanines substituted with 8-quinolinoxy moieties

被引：0
|
作者：
Li, Wei-Li [1 ]
Ma, Ji-Cheng [1 ]
Li, Wen-Ju [1 ]
Fu, Qiang [1 ]
Wang, Kun [1 ]
机构：
[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2011年 / 03期
关键词：
phthalocyanines; synthesis; 8-quinolinoxy; UV-Vis; fluorescence; NONLINEAR-OPTICAL PROPERTIES; MICROWAVE-ASSISTED SYNTHESIS; ELECTROCHEMISTRY; ZINC; METALLOPHTHALOCYANINES; FLUORESCENCE; COMPLEXES; COBALT;
D O I：
10.3184/174751911X12970818575209
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Peripherally tetraquinolinoxy-substituted, metal-free phthalocyanines and metallo-phthalocyanines 1c-f, 2c-f have been synthesised by reaction of an inorganic salt with phthalonitriles substituted with 5-(phenylamino)methyl-8-quinolinoxy and 5-[(4-chlorophenylamino) methyl]-8-quinolinoxy groups, respectively. The effects of metal ions [Zn(II), Cu(II), Co(II); N, i(II)], substituent, solvent and concentration on the UV-Vis spectra of these new complexes and their fluorescent properties are also described. The diamagnetic Zn(II) and Ni(II) complexes display intense fluorescence.
引用
收藏
页码：135 / 139
页数：5
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