Synthesis and spectroscopic properties of a series of metal-free and metallo-phthalocyanines substituted with 8-quinolinoxy moieties

被引：0

作者：

Li, Wei-Li ^{[1
]}

Ma, Ji-Cheng ^{[1
]}

Li, Wen-Ju ^{[1
]}

Fu, Qiang ^{[1
]}

Wang, Kun ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2011年 / 03期

关键词：

phthalocyanines; synthesis; 8-quinolinoxy; UV-Vis; fluorescence; NONLINEAR-OPTICAL PROPERTIES; MICROWAVE-ASSISTED SYNTHESIS; ELECTROCHEMISTRY; ZINC; METALLOPHTHALOCYANINES; FLUORESCENCE; COMPLEXES; COBALT;

D O I：

10.3184/174751911X12970818575209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Peripherally tetraquinolinoxy-substituted, metal-free phthalocyanines and metallo-phthalocyanines 1c-f, 2c-f have been synthesised by reaction of an inorganic salt with phthalonitriles substituted with 5-(phenylamino)methyl-8-quinolinoxy and 5-[(4-chlorophenylamino) methyl]-8-quinolinoxy groups, respectively. The effects of metal ions [Zn(II), Cu(II), Co(II); N, i(II)], substituent, solvent and concentration on the UV-Vis spectra of these new complexes and their fluorescent properties are also described. The diamagnetic Zn(II) and Ni(II) complexes display intense fluorescence.

引用

页码：135 / 139

页数：5

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