Coordination chemistry of P-rich phosphanes and silylphosphanes.: XXIV.: [1] formation and structure of [μ-(1,2:2-η-tBu2P-P){Mo(CO)2cp′}2]

被引：0

作者：

Krautscheid, H

Matern, E

Olkowska-Oetzel, J

Pikies, J

Fritz, G

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

[2] Gdansk Univ Technol, Fak Chem, PL-80952 Gdansk, Poland

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2001年 / 627卷 / 07期

关键词：

phosphorus; phosphinophosphinidene; molybdenum; NMR P-31{H-1} spectroscopy; mass spectroscopy; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[cp'Mo(CO)(2)](2) (cp' = (C5H4Bu)-Bu-t) reacts with (Bu2P)-Bu-t-P=P(Me)Bu-t(2) to yield the compound [mu-(1,2:2 eta-(Bu2P)-Bu-t-P) (Mo(CO)(2)cp'}(2)], which crystallizes in the space group P2(1)2(1)2(1) With a=1202.42(7), b=1552.48(8), and c=1765.3(1) pm.

引用

页码：1505 / 1507

页数：3

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