Coordination chemistry of P-rich phosphanes and silylphosphanes.: XXIV.: [1] formation and structure of [μ-(1,2:2-η-tBu2P-P){Mo(CO)2cp′}2]

被引:0
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作者
Krautscheid, H
Matern, E
Olkowska-Oetzel, J
Pikies, J
Fritz, G
机构
[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany
[2] Gdansk Univ Technol, Fak Chem, PL-80952 Gdansk, Poland
来源
关键词
phosphorus; phosphinophosphinidene; molybdenum; NMR P-31{H-1} spectroscopy; mass spectroscopy; crystal structure;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
[cp'Mo(CO)(2)](2) (cp' = (C5H4Bu)-Bu-t) reacts with (Bu2P)-Bu-t-P=P(Me)Bu-t(2) to yield the compound [mu-(1,2:2 eta-(Bu2P)-Bu-t-P) (Mo(CO)(2)cp'}(2)], which crystallizes in the space group P2(1)2(1)2(1) With a=1202.42(7), b=1552.48(8), and c=1765.3(1) pm.
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页码:1505 / 1507
页数:3
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