Palladium-Catalyzed C-H Aminations of Anilides with N-Fluorobenzenesulfonimide

被引:316
|
作者
Sun, Kai [1 ]
Li, Yan [1 ]
Xiong, Tao [1 ]
Zhang, Jingping [1 ]
Zhang, Qian [1 ]
机构
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
关键词
BOND FORMATION; FUNCTIONALIZATION; AMIDATION; ELECTRON; ARENES;
D O I
10.1021/ja1101695
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first amide-directed, palladium-catalyzed, intermolecular, highly selective C-H aminations with the non-nitrene-based nitrogen source N-fluorobenzenesulfonimide have been developed. This methodology might provide a new pathway for directed metal-catalyzed aromatic C-H amination.
引用
收藏
页码:1694 / 1697
页数:4
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