New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation

被引：4

作者：

Akbari, Alireza ^{[1
]}

Sheikhsoaei, Iran ^{[2
]}

Saghtforoush, Lotfali ^{[1
]}

Ebrahimipour, S. Yousof ^{[1
]}

Amiri, Zohreh ^{[1
]}

机构：

[1] Payame Noor Univ, Dept Chem, Tehran 193954697, Iran

[2] Shahid Bahonar Univ, Dept Chem, Kerman, Iran

来源：

E-JOURNAL OF CHEMISTRY | 2012年 / 9卷 / 04期

关键词：

Platinum(II); Schiff base; DFT; ADF; MOLECULAR-STRUCTURE; DONOR LIGANDS; CRYSTAL; PALLADIUM(II);

D O I：

10.1155/2012/802529

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetra dentate neutral (E)-4-nitro-2-((2-(2-(pyridin-2-yl) ethylthio) ethylimino) methyl) phenol, (pytaO(2)NSalH), Schiff-base ligand was synthesized using 1-(2-pyridyl)-3-thia-s-aminopentane (pyta) and 5-NO2 salicylaldehyde. Then the related square planar Pt (II) cationic complex, [Pt (NSNO)] Cl, was synthesized using PtCl2 (SMe2)(2) as precursor complex. The nature of the pytaO(2)NSalH and its platinum complex were determined by the elemental analysis, molar conductivity and spectrochemical (IR, UV-vis, (HNMR)-H-1) techniques. In addition, the fully optimized geometries and vibration frequencies of them together were calculated using the ADF 2009.01 package. Structural parameters are in good agreement with the experimental data. The calculated and experimental results confirmed the suggested structures for the ligand and complex.

引用

页码：2114 / 2118

页数：5

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