New Platinum(II) Complex Containing Asymmetric Tetra Dentate Schiff Base Ligand Synthesis, Characterization and DFT Calculation

被引：4

作者：

Akbari, Alireza ^{[1
]}

Sheikhsoaei, Iran ^{[2
]}

Saghtforoush, Lotfali ^{[1
]}

Ebrahimipour, S. Yousof ^{[1
]}

Amiri, Zohreh ^{[1
]}

机构：

[1] Payame Noor Univ, Dept Chem, Tehran 193954697, Iran

[2] Shahid Bahonar Univ, Dept Chem, Kerman, Iran

来源：

E-JOURNAL OF CHEMISTRY | 2012年 / 9卷 / 04期

关键词：

Platinum(II); Schiff base; DFT; ADF; MOLECULAR-STRUCTURE; DONOR LIGANDS; CRYSTAL; PALLADIUM(II);

D O I：

10.1155/2012/802529

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetra dentate neutral (E)-4-nitro-2-((2-(2-(pyridin-2-yl) ethylthio) ethylimino) methyl) phenol, (pytaO(2)NSalH), Schiff-base ligand was synthesized using 1-(2-pyridyl)-3-thia-s-aminopentane (pyta) and 5-NO2 salicylaldehyde. Then the related square planar Pt (II) cationic complex, [Pt (NSNO)] Cl, was synthesized using PtCl2 (SMe2)(2) as precursor complex. The nature of the pytaO(2)NSalH and its platinum complex were determined by the elemental analysis, molar conductivity and spectrochemical (IR, UV-vis, (HNMR)-H-1) techniques. In addition, the fully optimized geometries and vibration frequencies of them together were calculated using the ADF 2009.01 package. Structural parameters are in good agreement with the experimental data. The calculated and experimental results confirmed the suggested structures for the ligand and complex.

引用

页码：2114 / 2118

页数：5

共 50 条

[11] Schiff base ligand and metal (II) complex: Synthesis, characterization and biological evaluation
Panchani, Dipen
Thaker, Tirth
Lamse, Chaitali
INDIAN JOURNAL OF CHEMISTRY, 2025, 64 (02): : 165 - 171
[12] Synthesis and characterization of a tetranuclear copper(II) complex with a chiral Schiff base ligand
Xiang, Hua
Jiang, Long
Li, Huan-Yong
Zheng, Xiao-Dan
Li, Yu
CHINESE CHEMICAL LETTERS, 2013, 24 (01) : 49 - 51
[13] A novel schiff base ligand and its Ni(II) complex: synthesis and characterization
Gharamaleki, Jafar Attar
Bolouhari, Houra Sadat
Goodarzi, Atousa
Javadi, Ali
Notash, Behrouz
MONATSHEFTE FUR CHEMIE, 2016, 147 (12): : 2073 - 2081
[14] Synthesis, characterization and DFT calculations of N,O Schiff base complex of copper(II)
Dey, Sudipto
Ghosh, Koushik
Halder, Shibashis
Rizzoli, Corrado
Roy, Partha
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2015, 54 (12): : 1451 - 1458
[15] Synthesis, characterization, and DNA binding and cleavage properties of a platinum(II) Schiff base complex
Guitierrez, Luis A.
Rawji, Gulnar
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
[16] A new oxidovanadium(IV) Schiff base complex containing asymmetric tetradentate ONN′O′ Schiff base ligand: Synthesis, characterization, crystal structure determination, thermal study and catalytic activity
Grivani, Gholamhossein
Ghavami, Abbase
Eigner, Vaclav
Dusek, Michal
Khalaji, Aliakbar Dehno
CHINESE CHEMICAL LETTERS, 2015, 26 (06) : 779 - 784
[17] Synthesis, Characterization, and Bioactivity Studies of the Schiff Base Ligand and its Zinc(II) Complex
Salih, Nabaz A. Muhammad
ARO-THE SCIENTIFIC JOURNAL OF KOYA UNIVERSITY, 2024, 12 (02): : 108 - 114
[18] Zinc (II) complex with a cationic Schiff base ligand: Synthesis, characterization, and biological studies
Lee, Sze Koon
Tan, Kong Wai
Ng, Seik Weng
Ooi, Kah Kooi
Ang, Kok Pian
Abdah, Md Akim
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 121 : 101 - 108
[19] Synthesis, Characterization, and Bioactivity Studies of the Schiff Base Ligand and its Zinc(II) Complex
Salih, Nabaz A. Muhammad
ARO-THE SCIENTIFIC JOURNAL OF KOYA UNIVERSITY, 2024, 12 (01): : 108 - 114
[20] Asymmetric tridentate Schiff base ligand based mononuclear Zn(II) and Hg (II) complexes: Synthesis, structure, spectroscopic studies, thermal studies, and DFT calculation
Saren, Dama
Zangrando, Ennio
Manna, Subal Chandra
JOURNAL OF MOLECULAR STRUCTURE, 2025, 1321

← 1 2 3 4 5 →