Effects of two kinds of intercalated In films on quasi-free-standing monolayer graphene formed above SiC(0001)

被引:14
|
作者
Kim, Hidong [1 ,2 ,3 ]
Tsogtbaatar, Nyamaa [1 ,2 ]
Tuvdendorj, Bolortsetseg [1 ,2 ]
Lkhagvasuren, Altaibaatar [1 ,2 ]
Seo, Jae M. [1 ,2 ]
机构
[1] Chonbuk Natl Univ, Dept Phys, Jeonju 54896, South Korea
[2] Chonbuk Natl Univ, Inst Photon & Informat Technol, Jeonju 54896, South Korea
[3] Gwangju Inst Sci & Technol, Ctr Adv Xray Sci, Gwangju 61005, South Korea
基金
新加坡国家研究基金会;
关键词
ELECTRONIC-PROPERTIES; RECONSTRUCTION; 6H-SIC(0001); GRAPHITE;
D O I
10.1016/j.carbon.2019.12.032
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effects of In atoms intercalated between the n-type 6H-SiC(0001) substrate and the (6 root 3 x 6 root 3)R30 degrees zero layer (ZL) on the interface morphology, chemical composition and electron band structure were investigated by scanning tunneling microscopy (STM), low-energy electron diffraction (LEED), core-level/valence-band photoemission spectroscopy (PES) and angle-resolved photoemission spectroscopy (ARPES). As a result of In intercalation, two kinds of ordered In films depending on the thickness of In as well as the annealing temperature were formed under quasi-free-standing monolayer graphene (QFMLG) transformed from ZL. One is a bilayer film, which is stable under 800 degrees C. The other is a monolayer film composed of In adatoms of a (root 3 x root 3)R30 degrees structure, which survives over 800 degrees C. The latter induces electron doping of the QFMLG stronger than the former. In addition, the QFMLG on the (root 3 x root 3)R30 degrees film becomes more n-doped under higher annealing temperature, which is due to a vacancy increment of the In film. (C) 2019 Elsevier Ltd. All rights reserved.
引用
收藏
页码:229 / 235
页数:7
相关论文
共 50 条
  • [1] Reversible hydrogenation of deuterium-intercalated quasi-free-standing graphene on SiC(0001)
    Bocquet, F. C.
    Bisson, R.
    Themlin, J. -M.
    Layet, J. -M.
    Angot, T.
    PHYSICAL REVIEW B, 2012, 85 (20):
  • [2] Enhanced Raman spectra of hydrogen-intercalated quasi-free-standing monolayer graphene on 4H-SiC(0001)
    Grodecki, K.
    Jagiello, J.
    Dobrowolski, A.
    Czolak, D.
    Jozwik, I
    Ciuk, T.
    PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2020, 117
  • [3] Doping modulation of quasi-free-standing monolayer graphene formed on SiC(0001) through Sn1-xGex intercalation
    Kim, Hidong
    Dugerjav, Otgonbayar
    Lkhagvasuren, Altaibaatar
    Seo, Jae M.
    CARBON, 2019, 144 : 549 - 556
  • [4] The quasi-free-standing nature of graphene on H-saturated SiC(0001)
    Speck, F.
    Jobst, J.
    Fromm, F.
    Ostler, M.
    Waldmann, D.
    Hundhausen, M.
    Weber, H. B.
    Seyller, Th.
    APPLIED PHYSICS LETTERS, 2011, 99 (12)
  • [5] Formation of quasi-free-standing graphene on SiC(0001) through intercalation of erbium
    Bentley, P. D.
    Bird, T. W.
    Graham, A. P. J.
    Fossberg, O.
    Tear, S. P.
    Pratt, A.
    AIP ADVANCES, 2021, 11 (02)
  • [6] Charge neutrality of quasi-free-standing monolayer graphene induced by the intercalated Sn layer
    Kim, Hidong
    Dugerjav, Otgonbayar
    Lkhagvasuren, Altaibaatar
    Seo, Jae M.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2016, 49 (13)
  • [7] Bifunctional effects of the ordered Si atoms intercalated between quasi-free-standing epitaxial graphene and SiC(0001): graphene doping and substrate band bending
    Kim, Hidong
    Dugerjav, Otgonbayar
    Arvisbaatar, Amarmunkh
    Seo, Jae M.
    NEW JOURNAL OF PHYSICS, 2015, 17
  • [8] Fabricating Quasi-Free-Standing Graphene on a SiC(0001) Surface by Steerable Intercalation of Iron
    Shen, Kongchao
    Sun, Haoliang
    Hu, Jinping
    Hu, Huinbang
    Liang, Zhaofeng
    Li, Haiyang
    Zhu, Zhiyuan
    Huang, Yaobo
    Kong, Lingyuan
    Wang, Yu
    Jiang, Zheng
    Huang, Han
    Wells, Justin W.
    Song, Fei
    JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (37): : 21484 - 21492
  • [9] The impact of partial H intercalation on the quasi-free-standing properties of graphene on SiC(0001)
    Szary, Maciej J.
    El-Ahmar, Semir
    Ciuk, Tymoteusz
    APPLIED SURFACE SCIENCE, 2021, 541 (541)
  • [10] Quasi-Free-Standing Epitaxial Graphene on SiC (0001) by Fluorine Intercalation from a Molecular Source
    Wong, Swee Liang
    Huang, Han
    Wang, Yuzhan
    Cao, Liang
    Qi, Dongchen
    Santoso, Iman
    Chen, Wei
    Wee, Andrew Thye Shen
    ACS NANO, 2011, 5 (09) : 7662 - 7668