An efficient one-pot synthesis of 2-hydroxyalkyl dithiocarbamates

被引:24
|
作者
Cui, JL [1 ]
Ge, ZM [1 ]
Cheng, TM [1 ]
Li, RT [1 ]
机构
[1] Peking Univ, Sch Pharmaceut Sci, Dept Biol Chem, Beijing 100083, Haidian Dist, Peoples R China
关键词
2-hydroxyalkyl dithiocarbamate; ring opening of epoxide; regioselective reaction; anhydrous potassium phosphate; carbon disulfide;
D O I
10.1081/SCC-120021023
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In the presence of anhydrous potassium phosphate, epoxides reacted with carbon disulfide and primary or secondary amines in acetone to give the corresponding 2-hydroxyalkyl dithiocarbamates regioselectively in moderate to good yield.
引用
收藏
页码:1969 / 1976
页数:8
相关论文
共 50 条
  • [1] Convenient one-pot synthesis of vinyl ethers from phenyl 2-hydroxyalkyl selenides
    Sheng, SR
    Luo, HR
    Sun, WK
    Liu, XL
    Xin, Q
    Wang, QY
    SYNTHETIC COMMUNICATIONS, 2005, 35 (22) : 2839 - 2845
  • [2] A facile one-pot method for the synthesis of vinyl ethers from 2-hydroxyalkyl phenyl selenides
    Sheng, SR
    Luo, HR
    Sun, WK
    Huang, X
    CHINESE CHEMICAL LETTERS, 2005, 16 (11) : 1421 - 1423
  • [4] Facile one-pot synthesis of oxazolidin-2-ones from phenyl 2-hydroxyalkyl selenides
    Sheng, Shou-Ri
    Luo, Hai-Rong
    Huang, Zhen-Zhong
    Sun, Kang
    Liu, Xiao-Ling
    SYNTHETIC COMMUNICATIONS, 2007, 37 (16) : 2693 - 2699
  • [5] One-pot synthesis of vinyl phosphonates from 2-hydroxyalkyl phenyl selenides with monoethyl esters of phosphonic acid
    Sheng, Shou-Ri
    Sun, Wu-Kang
    Hu, Ming-Gang
    Liu, Xiao-Ling
    Wang, Qiu-Ying
    JOURNAL OF CHEMICAL RESEARCH-S, 2007, (02): : 97 - 99
  • [6] One-pot synthesis of dithiocarbamates accelerated in water
    Azizi, N
    Aryanasab, F
    Torkiyan, L
    Ziyaei, A
    Saidi, MR
    JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (09): : 3634 - 3635
  • [7] Convenient one-pot synthesis of symmetrical dithiocarbamates
    Nami, SAA
    Siddiqi, KS
    SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 2004, 34 (09): : 1581 - 1590
  • [8] One-Pot Convenient and High Yielding Synthesis of Dithiocarbamates
    Vinod K. Tiwari
    Archana Singh
    Hakkim A. Hussain
    Bhuwan B. Mishra
    Vyasji Tripathi
    Monatshefte für Chemie - Chemical Monthly, 2007, 138 : 653 - 658
  • [9] One-pot convenient and high yielding synthesis of dithiocarbamates
    Tiwari, Vinod K.
    Singh, Archana
    Hussain, Hakkim A.
    Mishra, Bhuwan B.
    Tripathi, Vyasji
    MONATSHEFTE FUR CHEMIE, 2007, 138 (07): : 653 - 658
  • [10] SYNTHESIS OF 2-HYDROXYALKYL METHACRYLATES
    IVKINA, AV
    TROFIMOV, VA
    BELOV, PS
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1974, 47 (09): : 2195 - 2196