Entropy minimization within the maximum entropy approach

被引:0
|
作者
Vakarin, E. V. [1 ]
Badiali, J. P. [1 ]
机构
[1] ENSCP Chim Paris Tech, CNRS, IRCP, UMR 8247, F-75231 Paris 05, France
关键词
D O I
10.1088/1742-6596/604/1/012017
中图分类号
O59 [应用物理学];
学科分类号
摘要
A procedure of the minimization of the maximum entropy with respect to an external driving force mu is proposed. In application to coupled dynamic-stochastic systems such an approach allows one to reduce the uncertainty in estimating the dynamic counterpart (a probe or a model) parameters. In its turn this permits to estimate an optimal driving path giving a maximal information on the probability distribution f(x vertical bar mu) of the stochastic counterpart with a given probe/model theta(mu vertical bar x). It is found that the functional form of the model should be similar to the observed/measured one theta(mu), while the minimum uncertainty is reached when the distribution becomes independent of the driving mu.
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页数:5
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