Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene

被引：4

作者：

Boganov, Sergey E. ^{[1
]}

Promyslov, Vladimir M. ^{[1
]}

Rynin, Stanislav S. ^{[1
]}

Krylova, Irina V. ^{[1
]}

Egorov, Mikhail P. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2018年 / 28卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

EXCITED-STATE; SILICON ATOMS; SILYLENES; CYCLOADDITION; CYCLOTRISILANE; DERIVATIVES;

D O I：

10.1016/j.mencom.2018.11.002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A matrix FTIR study of interaction between SiCl2 and 1,3-butadiene revealed that at low temperatures, it stops at the step of complexation between the reactants. This allowed us to investigate a photochemical version of this interaction resulting in the formation of both 1,1-dichloro-1-silacyclopent-3-ene and 1,1-dichloro-2-vinylsilirane in contrast to the thermal reaction giving only the first of these products.

引用

页码：574 / 576

页数：3

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