Formation of 1,1-dichloro-2-vinyl-1-silacyclopropane by a photoinduced reaction between dichlorosilylene and 1,3-butadiene

被引：4
|
作者：
Boganov, Sergey E. [1 ]
Promyslov, Vladimir M. [1 ]
Rynin, Stanislav S. [1 ]
Krylova, Irina V. [1 ]
Egorov, Mikhail P. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2018年 / 28卷 / 06期
基金：
俄罗斯科学基金会;
关键词：
EXCITED-STATE; SILICON ATOMS; SILYLENES; CYCLOADDITION; CYCLOTRISILANE; DERIVATIVES;
D O I：
10.1016/j.mencom.2018.11.002
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A matrix FTIR study of interaction between SiCl2 and 1,3-butadiene revealed that at low temperatures, it stops at the step of complexation between the reactants. This allowed us to investigate a photochemical version of this interaction resulting in the formation of both 1,1-dichloro-1-silacyclopent-3-ene and 1,1-dichloro-2-vinylsilirane in contrast to the thermal reaction giving only the first of these products.
引用
收藏
页码：574 / 576
页数：3
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