Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes

被引：15
|
作者：
Smith, Dan A. [1 ]
Batsanov, Andrei S. [1 ]
Costuas, Karine [3 ]
Edge, Ruth [2 ]
Apperley, David C. [1 ]
Collison, David [2 ]
Halet, Jean-Francois [3 ]
Howard, Judith A. K. [1 ]
Dyer, Philip W. [1 ]
机构：
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England
[3] Univ Rennes 1, CNRS, UMR 6226, Lab Sci Chim Rennes, Rennes, France
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 39期
基金：
英国工程与自然科学研究理事会;
关键词：
coordination chemistry; non-innocent ligands; P; N ligands; palladium; redox reactions; COUPLING REACTIONS; COOPERATIVE REACTIVITY; NONINNOCENT LIGAND; CRYSTAL-STRUCTURES; ARYL CHLORIDES; IMIDO COMPLEX; H BONDS; METAL; IMINOPHOSPHORANES; COORDINATION;
D O I：
10.1002/anie.201003946
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Is it or isn't it: Reaction of [PdMe2(tmeda)] with pyridyl-N-di(tert-butyl) phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand-based biradical complex, which behaves as a "masked" form of Pd0 in its reactions with neutral ligands and chlorobenzene. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：7040 / 7044
页数：5
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