Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes

被引：15

作者：

Smith, Dan A. ^{[1
]}

Batsanov, Andrei S. ^{[1
]}

Costuas, Karine ^{[3
]}

Edge, Ruth ^{[2
]}

Apperley, David C. ^{[1
]}

Collison, David ^{[2
]}

Halet, Jean-Francois ^{[3
]}

Howard, Judith A. K. ^{[1
]}

Dyer, Philip W. ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[3] Univ Rennes 1, CNRS, UMR 6226, Lab Sci Chim Rennes, Rennes, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 39期

基金：

英国工程与自然科学研究理事会;

关键词：

coordination chemistry; non-innocent ligands; P; N ligands; palladium; redox reactions; COUPLING REACTIONS; COOPERATIVE REACTIVITY; NONINNOCENT LIGAND; CRYSTAL-STRUCTURES; ARYL CHLORIDES; IMIDO COMPLEX; H BONDS; METAL; IMINOPHOSPHORANES; COORDINATION;

D O I：

10.1002/anie.201003946

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Is it or isn't it: Reaction of [PdMe2(tmeda)] with pyridyl-N-di(tert-butyl) phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand-based biradical complex, which behaves as a "masked" form of Pd0 in its reactions with neutral ligands and chlorobenzene. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7040 / 7044

页数：5

共 50 条

[21] Non-innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes
Ehret, Fabian
Bubrin, Martina
Zalis, Stanislav
Kaim, Wolfgang
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2014, 640 (14): : 2781 - 2787
[22] Geometric and Electronic Structures of Ni(II) Complexes of Non-Innocent Tetradentate Phenylenediamine Ligands
Leconte, N.
Ciccione, J.
Philouze, C.
Thomas, F.
Orio, M.
JOURNAL OF BIOLOGICAL INORGANIC CHEMISTRY, 2014, 19 : S509 - S509
[23] Chelate rings of different sizes with non-innocent ligands
Kaim, Wolfgang
DALTON TRANSACTIONS, 2019, 48 (24) : 8521 - 8529
[24] INOR 798-Ruthenium complexes with non-innocent o-iminoquinonoid ligands
Rochford, Jonathan
Tsai, Ming-Kang
Muckerman, James T.
Fujita, Etsuko
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 236
[25] Artificial hydrogenases: Utilization of peptide and redox non-innocent ligands in [FeFe] and [NiFe] complexes
Roy, Souvik
Gan, Lu
Dutta, Arnab
Hamilton, G. Alexander
Groy, Thomas
Hartnett, Hilairy E.
Jones, Anne K.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
[26] INOR 335-Competition between different non-innocent ligands in metal complexes
Kaim, Wolfgang
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 236
[27] Joint spectroscopic and theoretical investigations of transition metal complexes involving non-innocent ligands
Ray, Kallol
Petrenko, Taras
Wieghardt, Karl
Neese, Frank
DALTON TRANSACTIONS, 2007, (16) : 1552 - 1566
[28] Coordination of non-innocent nitrogen oxide ligands: terminology
Katrina M. Miranda
JBIC Journal of Biological Inorganic Chemistry, 2019, 24 : 315 - 316
[29] Non-Innocent Ligands: New Opportunities in Iron Catalysis
Blanchard, Sebastien
Derat, Etienne
Desage-El Murr, Marine
Fensterbank, Louis
Malacria, Max
Mouries-Mansuy, Virginie
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (03) : 376 - 389
[30] Next generation redox-active "ligands" from non-innocent coordination complexes
Heyduk, Alan
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249

← 1 2 3 4 5 →