Exploiting Non-Innocent Ligands to Prepare Masked Palladium(0) Complexes

被引：15

作者：

Smith, Dan A. ^{[1
]}

Batsanov, Andrei S. ^{[1
]}

Costuas, Karine ^{[3
]}

Edge, Ruth ^{[2
]}

Apperley, David C. ^{[1
]}

Collison, David ^{[2
]}

Halet, Jean-Francois ^{[3
]}

Howard, Judith A. K. ^{[1
]}

Dyer, Philip W. ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[3] Univ Rennes 1, CNRS, UMR 6226, Lab Sci Chim Rennes, Rennes, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 39期

基金：

英国工程与自然科学研究理事会;

关键词：

coordination chemistry; non-innocent ligands; P; N ligands; palladium; redox reactions; COUPLING REACTIONS; COOPERATIVE REACTIVITY; NONINNOCENT LIGAND; CRYSTAL-STRUCTURES; ARYL CHLORIDES; IMIDO COMPLEX; H BONDS; METAL; IMINOPHOSPHORANES; COORDINATION;

D O I：

10.1002/anie.201003946

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Is it or isn't it: Reaction of [PdMe2(tmeda)] with pyridyl-N-di(tert-butyl) phosphinoimine spontaneously affords an unusual bimetallic palladium(I) ligand-based biradical complex, which behaves as a "masked" form of Pd0 in its reactions with neutral ligands and chlorobenzene. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7040 / 7044

页数：5

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