Synthesis and structure of hexaaquacobalt bis(2-methyl-1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato-κO)cobalt

被引：0
|
作者：
Velazquez-Garcia, Jose de Jesus [1 ]
Techert, Simone [1 ,2 ]
机构：
[1] DESY, Notkestr 85, D-22607 Hamburg, Germany
[2] Georg August Univ Gottingen, Inst Rontgenphys, Friedrich Hund Pl 1, D-37077 Gottingen, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷
关键词：
crystal structure; hexaaqua-cobalt; 2-methylimidazole; 1,3,5-benzene tricarboxylic acid; GRAPH-SET ANALYSIS; TRANSITION; COMPLEXES; PATTERNS;
D O I：
10.1107/S2056989022007046
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, (C4H7N2)(2)[Co(H2O)(6)][Co(C9H3O6)(2)(H2O)(4)] (1), was synthesized from cobalt(II) chloride, 1,3,5-benzene tricarboxylic acid (Hbtc) and 2-methyl-imidazole (H-2mIm) under ambient conditions. The structure of 1 is here reported and compared with the parent complex hexaaquacobalt bis(1H-imidazol-3-ium) tetraaquabis(benzene-1,3,5-tricarboxylato)cobalt (2).
引用
收藏
页码：814 / +
页数：10
相关论文
共 50 条
  • [1] Crystal structure of bis(2-methyl-1H-imidazol-3-ium) tetrachloridocobaltate(II)
    Diop, Mouhamadou Birame
    Diop, Libasse
    Maris, Thierry
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 1064 - +
  • [2] Crystal structure of 2-methyl-1H-imidazol-3-ium hydrogen oxalate dihydrate
    Diop, Mouhamadou Birame
    Diop, Libasse
    Plasseraud, Laurent
    Cattey, Helene
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1113 - +
  • [3] Crystal structure of 2-methyl-1H-imidazol-3-ium 3,5-dicarboxybenzoate
    Baletska, Sofiia
    Techert, Simone
    Velazquez-Garcia, Jose de Jesus
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2023, 79 : 1088 - +
  • [4] Triorganotin carboxylates - synthesis and crystal structure of 2-methyl-1H-imidazol-3-ium catena-O, O′-oxalatotriphenylstannate
    Diop, Mouhamadou Birame
    Diop, Libasse
    Plasseraud, Laurent
    Cattey, Helene
    MAIN GROUP METAL CHEMISTRY, 2016, 39 (3-4) : 119 - 123
  • [5] Crystal structures of the two salts 2-methyl-1H-imidazol-3-ium nitrate-2-methyl-1H-imidazole (1/1) and 2-methyl-1H-imidazol-3-ium nitrate
    Diop, Mouhamadou Birame
    Diop, Libasse
    Maris, Thierry
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 482 - +
  • [6] Bis(2-methyl-1H-imidazol-3-ium)naphthalene-1,5-disulfonate dihydrate
    Wang, Yu-feng
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1619 - +
  • [7] Crystal structure of bis(2-methyl-1H-imidazol-3-ium) mu-oxalato-bis[n-butyltrichloridostannate(IV)]
    Diop, Mouhamadou Birame
    Diop, Libasse
    Oliver, Allen G.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 858 - +
  • [8] Poly[bis(μ3-benzene-1,3,5-tricarboxylato-κ3O1:O3:O5) tris[μ2-1,3-bis(imidazol-1-ylmethyl)benzene-κ2N:N′] tricobalt(II)] and poly[[diaquabis(μ3-benzene-1,3,5-tricarboxylato-κ3O1:O3:O5)tris[μ2-1,4-bis(imidazol-1-ylmethyl) benzene-κ2N:N′] tricobalt(II)] monohydrate]
    Liu, Ying-Ying
    Yang, Jin
    Ma, Ji-Cheng
    Ma, Jian-Fang
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2008, 64 : M33 - M36
  • [9] Crystal structure of 2-methyl-1H-imidazol-3-ium aquatrichlorido(oxalato-kappa O-2,O ')stannate(IV)
    Diop, Mouhamadou Birame
    Diop, Libasse
    Plasscraud, Laurent
    Maris, Thierry
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 520 - +
  • [10] Crystal structure of bis(2-methyl-1H-imidazol-3-ium) dihydroxidobis(oxalato-kappa O-2(1),O-2)stannate(IV) monohydrate
    Diop, Mouhamadou Birame
    Diop, Libasse
    Plasseraud, Laurent
    Maris, Thierry
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 355 - +
12345