Theoretical and experimental studies of chiral recognition in charged pirkle phases

被引:4
|
作者
Lee, OS
Jang, YH
Cho, YG
Hyun, MH
Kim, HJ
Chung, DS [1 ]
机构
[1] Seoul Natl Univ, Sch Chem, Seoul 151747, South Korea
[2] Pusan Natl Univ, Dept Chem, Pusan 609753, South Korea
关键词
D O I
10.1246/cl.2001.232
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The role of electrostatic interactions in enantioselective separation was demonstrated. Enantioselective separation of N(3,5-dinitrobenzoyl)leucine and its esterified analogue was investigated by (S)-phenylglycine-based HPLC under an intermediate pH, and examined with a relaxed scan calculation combined with a Monte Carlo conformation search.
引用
收藏
页码:232 / 233
页数:2
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