Crystal structure of the 2:1 complex of 2,6-dichloro-4-nitrophenol with 1,4-dioxane

被引：0
|
作者：
Kose, M. [1 ]
Ceyhan, G. [1 ]
Purtas, S. [1 ]
Tumer, M. [1 ]
McKee, V. [2 ]
机构：
[1] K Maras Sutcu Imam Univ, Dept Chem, TR-46100 K Maras, Turkey
[2] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 08期
关键词：
2,6-dichloro-4-nitrophenol; 1,4-dioxane; X-ray; hydrogen bonding;
D O I：
10.1134/S0022476614080320
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystal structure of a complex of 2,6-dichloro-4-nitrophenol (DCNP) with 1,4-dioxane is reported. Single crystals suitable for X-ray diffraction study was obtained by slow evaporation of a solution of DCNP in 1,4-dioxane. X-ray structure determination showed that the compound crystallizes in the monoclinic space group P2(1)/n with cell parameters a = 11.9935(7) , b = 5.1491(3) , c = 16.8775(10) , beta = 105.9360(10)A degrees, V = 1002.23(10) (3) and Z = 4. In the structure, the molecules lie about an inversion centre and asymmetric unit contains half of the structure. Two molecules of DCNP moiety are connected by an 1,4-dioxane molecule via strong hydrogen bonding.
引用
收藏
页码：1623 / 1626
页数：4
相关论文
共 50 条
  • [31] Cooperative hydrogen bond between piperidine-ethanol and 2,6-dichloro-4-nitrophenol
    Dega-Szafran, Zofia
    Bartoszak-Adamska, Elzbieta
    Baranowska, Anna
    Komasa, Anna
    Szafran, Miroslaw
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1184 : 468 - 478
  • [32] STRUCTURE OF CATENA-DICHLORO-MU-(1,4-DIOXANE-O,O')-(1,4-DIOXANE)ZINC(II), [ZN(C4H8O2)2CL2]
    BOARDMAN, A
    SMALL, RWH
    WORRALL, IJ
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1983, 39 (AUG) : 1005 - 1007
  • [33] STRUCTURE OF 1-1 COMPLEX OF MERCURY(II) TRIFLUOROACETATE AND 1,4-DIOXANE
    SMALL, RWH
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (NOV): : 2886 - 2887
  • [34] ON THE REACTION OF 2,3-DICHLORO-1,4-DIOXANE WITH MERCAPTANS
    PROSTENIK, M
    BALENOVIC, K
    JOURNAL OF ORGANIC CHEMISTRY, 1952, 17 (03): : 379 - 380
  • [35] The crystal structure and theoretical study of styphnic/1,4-dioxane solvate
    Chen, Peng-Yuan, 1600, China Ordnance Industry Corporation (35):
  • [36] 1,4-dioxane neodymium nitrate complex: Structure and spectral properties
    Medvedev, YN
    Kuznetsov, ML
    Lysenko, KA
    Antipin, MY
    Lokshin, BV
    ZHURNAL NEORGANICHESKOI KHIMII, 1998, 43 (03): : 430 - 437
  • [37] STRUCTURE OF CRYSTALLINE SOLVATE OF 2,4,5,7-TETRANITROFLUORENE WITH 1,4-DIOXANE
    SEMIDETKO, OV
    CHYOTKINA, LA
    BELSKII, VK
    ANRIEVSKII, AM
    KRAVCHENKO, NV
    KRISTALLOGRAFIYA, 1988, 33 (05): : 1294 - 1296
  • [38] UI4(1,4-dioxane)2, [UCl4(1,4-dioxane)]2, and UI3(1,4-dioxane)1.5: Stable and Versatile Starting Materials for Low- and High-Valent Uranium Chemistry
    Monreal, Marisa J.
    Thomson, Robert K.
    Cantat, Thibault
    Travia, Nicholas E.
    Scott, Brian L.
    Kiplinger, Jaqueline L.
    ORGANOMETALLICS, 2011, 30 (07) : 2031 - 2038
  • [39] Synthesis and crystal structure of 2,3-bis(dinitro-fluoromethyl)-1,4-dioxane
    Fedorov B.S.
    Golovina N.I.
    Smirnov S.P.
    Abdrakhmanov I.Sh.
    Firkin A.I.
    Atovmyan L.O.
    Chemistry of Heterocyclic Compounds, 2002, 38 (4) : 385 - 389
  • [40] Dynamic CuCl2-(1,4-dioxane)-H2O Crystal
    Zhang, Yan
    Zhang, Bin
    Zhu, Daoben
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C641 - C641
12345