Crystal structure of the 2:1 complex of 2,6-dichloro-4-nitrophenol with 1,4-dioxane

被引：0
|
作者：
Kose, M. [1 ]
Ceyhan, G. [1 ]
Purtas, S. [1 ]
Tumer, M. [1 ]
McKee, V. [2 ]
机构：
[1] K Maras Sutcu Imam Univ, Dept Chem, TR-46100 K Maras, Turkey
[2] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 08期
关键词：
2,6-dichloro-4-nitrophenol; 1,4-dioxane; X-ray; hydrogen bonding;
D O I：
10.1134/S0022476614080320
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystal structure of a complex of 2,6-dichloro-4-nitrophenol (DCNP) with 1,4-dioxane is reported. Single crystals suitable for X-ray diffraction study was obtained by slow evaporation of a solution of DCNP in 1,4-dioxane. X-ray structure determination showed that the compound crystallizes in the monoclinic space group P2(1)/n with cell parameters a = 11.9935(7) , b = 5.1491(3) , c = 16.8775(10) , beta = 105.9360(10)A degrees, V = 1002.23(10) (3) and Z = 4. In the structure, the molecules lie about an inversion centre and asymmetric unit contains half of the structure. Two molecules of DCNP moiety are connected by an 1,4-dioxane molecule via strong hydrogen bonding.
引用
收藏
页码：1623 / 1626
页数：4
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