Crystal structure of the 2:1 complex of 2,6-dichloro-4-nitrophenol with 1,4-dioxane

被引：0

作者：

Kose, M. ^{[1
]}

Ceyhan, G. ^{[1
]}

Purtas, S. ^{[1
]}

Tumer, M. ^{[1
]}

McKee, V. ^{[2
]}

机构：

[1] K Maras Sutcu Imam Univ, Dept Chem, TR-46100 K Maras, Turkey

[2] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 08期

关键词：

2,6-dichloro-4-nitrophenol; 1,4-dioxane; X-ray; hydrogen bonding;

D O I：

10.1134/S0022476614080320

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystal structure of a complex of 2,6-dichloro-4-nitrophenol (DCNP) with 1,4-dioxane is reported. Single crystals suitable for X-ray diffraction study was obtained by slow evaporation of a solution of DCNP in 1,4-dioxane. X-ray structure determination showed that the compound crystallizes in the monoclinic space group P2(1)/n with cell parameters a = 11.9935(7) , b = 5.1491(3) , c = 16.8775(10) , beta = 105.9360(10)A degrees, V = 1002.23(10) (3) and Z = 4. In the structure, the molecules lie about an inversion centre and asymmetric unit contains half of the structure. Two molecules of DCNP moiety are connected by an 1,4-dioxane molecule via strong hydrogen bonding.

引用

页码：1623 / 1626

页数：4

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