Tunable P-Stereogenic P,N-Phosphine Ligands Design: Synthesis and Coordination Chemistry to Palladium

被引：3

作者：

Lemouzy, Sebastien ^{[1
]}

Jean, Marion ^{[1
]}

Deplante, Fabien ^{[1
]}

Albalat, Muriel ^{[1
]}

Herault, Damien ^{[1
]}

Buono, Gerard ^{[1
]}

机构：

[1] Aix Marseille Univ, CNRS, Cent Marseille, iSm2, Marseille, France

来源：

CHEMISTRYSELECT | 2018年 / 3卷 / 43期

关键词：

complexes synthesis; heterobidentate ligand; P-chiral; palladium; phosphorus; ALPHA-ARYLATION; ASYMMETRIC-SYNTHESIS; HYBRID LIGANDS; P; N LIGANDS; COMPLEXES; PHOSPHINE; KETONES; ENANTIOSELECTIVITY; N-LIGANDS; DIPHOSPHINE;

D O I：

10.1002/slct.201803376

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of P,N heterobidentate phosphine / palladium complexes has been realized from P-stereogenic enantiopure ligands. Five, six or seven membered ring complexes have been fully characterized, notably by X-ray diffraction, allowing the study of the chelation to a "palladium (II) dichloride" unit. The nature of nitrogen coordination site as well as the size of the ring modify the bite-angle at the solid state.

引用

页码：12281 / 12286

页数：6

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