Tunable P-Stereogenic P,N-Phosphine Ligands Design: Synthesis and Coordination Chemistry to Palladium

被引：3
|
作者：
Lemouzy, Sebastien [1 ]
Jean, Marion [1 ]
Deplante, Fabien [1 ]
Albalat, Muriel [1 ]
Herault, Damien [1 ]
Buono, Gerard [1 ]
机构：
[1] Aix Marseille Univ, CNRS, Cent Marseille, iSm2, Marseille, France
来源：
CHEMISTRYSELECT | 2018年 / 3卷 / 43期
关键词：
complexes synthesis; heterobidentate ligand; P-chiral; palladium; phosphorus; ALPHA-ARYLATION; ASYMMETRIC-SYNTHESIS; HYBRID LIGANDS; P; N LIGANDS; COMPLEXES; PHOSPHINE; KETONES; ENANTIOSELECTIVITY; N-LIGANDS; DIPHOSPHINE;
D O I：
10.1002/slct.201803376
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of P,N heterobidentate phosphine / palladium complexes has been realized from P-stereogenic enantiopure ligands. Five, six or seven membered ring complexes have been fully characterized, notably by X-ray diffraction, allowing the study of the chelation to a "palladium (II) dichloride" unit. The nature of nitrogen coordination site as well as the size of the ring modify the bite-angle at the solid state.
引用
收藏
页码：12281 / 12286
页数：6
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