Synthesis of chiral sulfoximines derived from 3-aminoquinazolinones and their catalysis of enantioselective diethylzinc addition to aldehydes

被引：7

作者：

Karabuga, Semistan ^{[2
]}

Cakici, Murat ^{[3
]}

Kazaz, Cavit ^{[3
]}

Sahin, Ertan ^{[3
]}

Kilic, Hamdullah ^{[3
]}

Ulukanli, Sabri ^{[1
]}

机构：

[1] Osmaniye Korkut Ata Univ, Fac Sci & Letters, Dept Chem, TR-80000 Osmaniye, Turkey

[2] Kahramanmaras Sutcu Imam Univ, Fac Sci & Letters, Dept Chem, TR-46100 Kahramanmaras, Turkey

[3] Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 22期

关键词：

CONTROLLED DIASTEREOSELECTIVE AZIRIDINATION; TRANSITION-STATE GEOMETRY; ASYMMETRIC-SYNTHESIS; C-1-SYMMETRIC AMINOSULFOXIMINES; BUTHIONINE SULFOXIMINE; STYRENE DERIVATIVES; LIGANDS; ALKENES; BENZOTHIAZINES; 3-ACETOXYAMINOQUINAZOLINONES;

D O I：

10.1039/c1ob06205k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of sulfoxides were sulfoximinated using oxidative addition of 3-aminoquinazolinones by lead tetraacetate in the presence of hexamethyldisilazane. They were applied for the first time in catalytic enantioselective addition to aromatic aldehydes with a product enantiopurity (ee) of 92% in the case of 2-methoxybenzaldehyde.

引用

页码：7887 / 7896

页数：10

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