Structural morphology of poly(urethane semicarbazide)-poly(vinyl pyrrolidone) blends

被引:0
|
作者
Shtompel', VI [1 ]
Kercha, YY [1 ]
Sukhorukova, SA [1 ]
Levchenko, NI [1 ]
Karabanova, LV [1 ]
机构
[1] Natl Acad Sci Ukraine, Inst Macromol Chem, UA-02160 Kiev, Ukraine
关键词
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Structural morphology of a series of blends of poly(urethane semicarbazide) (PUS) and poly(vinyl pyrrolidone) (PVP) was studied by X-ray diffraction and dilatometry. As the PVP fraction in the blend increases from 0 to 100 wt %, the structural organization parameters vary in an extremal manner with a maximum observed at 30 wt % PVP. The PUS-PVP blends exhibit interaction between the tertiary nitrogen atoms of PVP and the COOH groups of PUS, which lead to the formation of ion groups and interpolymer complexes.
引用
收藏
页码:21 / 25
页数:5
相关论文
共 50 条
  • [21] Dynamic mechanical characterization of hydrogel blends of poly(vinyl alcohol-vinyl acetate) with poly(acrylic acid) or poly(vinyl pyrrolidone)
    CauichRodriguez, JV
    Deb, S
    Smith, R
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1996, 7 (06) : 349 - 353
  • [22] Solvent effects on the dielectric dispersion of poly(vinyl pyrrolidone)-poly(ethylene glycol) blends
    R. J. Sengwa
    Sonu Sankhla
    Colloid and Polymer Science, 2007, 285 : 1237 - 1246
  • [23] Solvent effects on the dielectric dispersion of poly(vinyl pyrrolidone)-poly(ethylene glycol) blends
    Sengwa, R. J.
    Sankhla, Sonu
    COLLOID AND POLYMER SCIENCE, 2007, 285 (11) : 1237 - 1246
  • [24] Morphology, drug release behavior, thermal, and mechanical properties of poly(ethylene oxide) (PEO)/poly(vinyl pyrrolidone) (PVP) blends
    Sedeh, Negar Naghdi
    Entezam, Mehdi
    Jafari, Seyed Hassan
    Khonakdar, Hossein-Ali
    Abdouss, Majid
    JOURNAL OF APPLIED POLYMER SCIENCE, 2018, 135 (26)
  • [25] Morphology, drug release behavior, thermal, and mechanical properties of poly(ethylene oxide) (PEO)/poly(vinyl pyrrolidone) (PVP) blends
    Entezam, Mehdi (mehdi.entezam@gmail.com), 1600, John Wiley and Sons Inc, Postfach 10 11 61, 69451 Weinheim, Boschstrabe 12, 69469 Weinheim, Deutschland, 69469, Germany (135):
  • [26] Morphology and viscoelastic properties of poly(vinyl chloride)/poly(vinyl alcohol) incompatible blends
    Takeuchi, Kazuma
    Kamaguchi, Akihiro
    Nabeta, Muneaki
    Fujii, Syuji
    Nakamura, Yoshinobu
    Iida, Takeo
    POLYMERS & POLYMER COMPOSITES, 2007, 15 (05): : 371 - 377
  • [27] Super-tough biodegradable poly(vinyl alcohol)/poly(vinyl pyrrolidone) blends plasticized by glycerol and sorbitol
    Chaibundit, Chiraphon (chiraphon.c@psu.ac.th), 1600, John Wiley and Sons Inc, Postfach 10 11 61, 69451 Weinheim, Boschstrabe 12, 69469 Weinheim, Deutschland, 69469, Germany (135):
  • [28] Biocompatible polymer blends: Effects of physical processing on the molecular interaction of poly(vinyl alcohol) and poly(vinyl pyrrolidone)
    Jones, S.A.
    Martin, G.P.
    Royall, P.G.
    Brown, M.B.
    Journal of Applied Polymer Science, 2005, 98 (05): : 2290 - 2299
  • [29] Crystallization kinetics and morphology of poly(β-hydroxybutyrate) and poly(vinyl acetate) blends
    Polymer Physics Laboratory, Changchun Inst. of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China
    Eur Polym J, 9 (1449-1452):
  • [30] Blends of Poly(vinyl alcohol) and Poly(vinyl pyrrolidone): Interrelation between the Degree of Hydration and Thermal and Mechanical Properties
    Oikonomou, Petros
    Sanopoulou, Merope
    Papadokostaki, Kyriaki G.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2021, 60 (39) : 14203 - 14212