Hollow biomorphic Al2O3 fibers produced from sisal

被引:7
|
作者
Andrade, Tarcisio E., Jr.
Rambo, Carlos Renato
Sieber, Heino
Martinelli, Antonio E. [1 ]
Melo, Dulce Maria A.
机构
[1] Univ Fed Rio Grande do Norte, Dept Chem, BR-59072970 Natal, RN, Brazil
[2] Univ Fed Santa Catarina, Dept Chem Engn, BR-88040900 Florianopolis, SC, Brazil
[3] Univ Erlangen Nurnberg, Dept Mat Sci Glass & Ceram, D-91058 Erlangen, Germany
关键词
D O I
10.1007/s10853-006-0772-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Al2O3 fibers with a hollow morphology were produced by Al-vapor infiltration-reaction and subsequent oxidation from pyrolysed fibers of natural sisal. Following pyrolysis, the bio-fiber template was reacted with gaseous Al at 1,400 degrees C-1,600 degrees C in vacuum to form Al4C3. After an oxidation/sintering process at 1,550 degrees C, the biomorphic Al4C3 fibers were fully converted into Al2O3, maintaining the microstructural features of the native sisal. Phase and microstructural characterization during processing were evaluated by high temperature X-ray diffractometry and scanning electron microscopy, respectively. Thermo-analyses were performed in the Al4C3 samples in order to estimate the reactions and the weight change during the oxidation step.
引用
收藏
页码:5426 / 5430
页数:5
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