cis-(2,2′-bipyridine)bis[2-(2-pyridyl)-4-methoxy-carbonylquinoline]ruthenium(II) hexafluorophosphate

被引：5
|
作者：
Farah, AA
Zobi, F
Stynes, DV
Lough, AJ
Pietro, WJ
机构：
[1] York Univ, Dept Chem, N York, ON M3J 1P3, Canada
[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷
关键词：
D O I：
10.1107/S1600536801008765
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Ru atom of the title compound, [Ru(C16H12N2O2)(2)(C10H8N2)](PF6)(2), is octahedrally coordinated to the N atoms of 2-(2-pyridyl)-4-methoxycarbonylquinoline and to those of a bipyridine ligand which are cis to each other. Owing to the rigidity of the 2-(2-pyridyl)-4-methoxycarbonylquinoline ligand, the complex is a distorted octahedron with Ru-N distances of 2.119 (2), 2.062 (2) and 2.043 (2) Angstrom. Half a complex cation and one hexafluorophosphate counter-ion form the asymmetric unit. The complex cation lies on a twofold axis running along the line joining the Ru atom and the midpoint of the C17-C17(-x, y, 1/2-z) bond.
引用
收藏
页码：m274 / m276
页数：3
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