Bis(2,2′-bipyridine)[2-(2-pyridyl)-1H-benzimidazol-1-yl]ruthenium(II) perchlorate acetonitrile solvate monohydrate

被引：3
|
作者：
Liu, YJ
Chao, H [1 ]
Yu, HJ
Yuan, YX
Ji, LN
机构：
[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China
[2] Coll Pharm, Dept Pharm, Guangzhou 510240, Guangdong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806005459
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Ru(C12H8N3)(C10H8N2)(2)] ClO(4)center dot CH3CN center dot-H2O, was grown by diethyl ether diffusion into an acetonitrile solution from acetonitrile at room temperature. The Ru-II ion is in a distorted octahedral environment coordinated by two 2,2'-bipyridine (bpy) and one deprotonated 2-(2-pyridyl) benzimidazole (PIB) ligand. Charge is balanced by a perchlorate counter-ion. The free water molecule links an O atom of the perchlorate ion and the uncoordinated N atom of the ligand PIB by hydrogen bond.
引用
收藏
页码：M585 / M587
页数：3
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