Redetermination of cis-diacetonitrile-bis(2,2′-bipyridine)ruthenium(II) hexafluorophosphate

被引：7
|
作者：
Xu, Feng
Huang, Wei [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Dept Chem & Chem Engn, Nanjing 210008, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Jinchuan Grp Ltd, Joint Lab Met Chem, Nanjing 210093, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S1600536807033065
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Ru(C10H8N2)(2)(CH3CN)(2)](PF6)(2), a six-coordinate ruthenium(II) complex, crystallizes in the monoclinic C2/c space group showing different symmetry from the previously reported P2(1)/n. A crystallographic twofold rotation axis passes through the Ru atom. The two C atoms and H atoms of one acetonitrile ligand are disordered over two positions, with site occupancy factors of ca 0.55 and 0.45. Three F atoms are disordered over two positions, with similar site occupancy factors.
引用
收藏
页码：M2114 / U806
页数：9
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