Bis(μ-thiophene-2-carbaldehyde thiosemicarbazonato) bis[acetonitrilecopper(I)] bis(tetrafluoroborate)

被引:6
|
作者
Pike, RD [1 ]
Wiles, AB [1 ]
Tronic, TA [1 ]
机构
[1] Coll William & Mary, Dept Chem, Williamsburg, VA 23187 USA
关键词
D O I
10.1107/S1600536806001887
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu-2(C6H7N3S2)(2)(C2H3N)(2)](BF4)(2), is a dimer with a central Cu2S2 core resulting from thiosemicarbazone sulfur bridging. Both Cu-TCT units (TCT is the thiophene-2-carboxaldehyde thiosemicarbazone anion) are roughly planar and are parallel to one another and perpendicular to the Cu2S2 plane.
引用
收藏
页码:M347 / M349
页数:3
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