Bis(μ-thiophene-2-carbaldehyde thiosemicarbazonato) bis[acetonitrilecopper(I)] bis(tetrafluoroborate)

被引：6
|
作者：
Pike, RD [1 ]
Wiles, AB [1 ]
Tronic, TA [1 ]
机构：
[1] Coll William & Mary, Dept Chem, Williamsburg, VA 23187 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806001887
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu-2(C6H7N3S2)(2)(C2H3N)(2)](BF4)(2), is a dimer with a central Cu2S2 core resulting from thiosemicarbazone sulfur bridging. Both Cu-TCT units (TCT is the thiophene-2-carboxaldehyde thiosemicarbazone anion) are roughly planar and are parallel to one another and perpendicular to the Cu2S2 plane.
引用
收藏
页码：M347 / M349
页数：3
相关论文
共 50 条
  • [21] Thiophene-2-carbaldehyde 2,4-dinitrophenylhydrazone
    Yin, Zhi-gang
    Qian, Heng-yu
    Li, He-ping
    Hu, Jie
    Zhang, Chun-xia
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O2421 - U3136
  • [22] Bis(μ-2-cyanopyridine-N:N′)bis[(2-cyanopyridine-N)silver(I)]bis(tetrafluoroborate):: an anion-linked molecular ladder
    Blake, AJ
    Champness, NR
    Nicolson, JEB
    Wilson, C
    ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 : 1290 - 1291
  • [23] Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]-bis[(1,10-phenanthroline-κ2N, N′)copper(I)] bis(tetrafluoroborate) dichloromethane disolvate
    Liu, HY
    Wang, FY
    Wang, GY
    Huang, CG
    Peng, DY
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M111 - M112
  • [24] Inhibition of respiratory Complex I by copper(II)-bis(thiosemicarbazonato) complexes
    Djoko, Karrera Y., 1600, Royal Society of Chemistry (06):
  • [25] Synthesis, characterization and crystal structure analysis of bis (pyridine-2-carbaldehyde thiosemicarbazonato)cobalt(III) thiocyanate monohydrate
    Chattopadhyay, SK
    Banerjee, T
    Roychoudhury, P
    Mak, TCW
    Ghosh, S
    TRANSITION METAL CHEMISTRY, 1997, 22 (03) : 216 - 219
  • [26] Bis[N-(2-aminoethyl)morpholine]copper(II)bis(tetrafluoroborate)
    Sander, O
    Tuczek, F
    Näther, C
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M824 - M825
  • [27] Inhibition of respiratory Complex I by copper(II)-bis(thiosemicarbazonato) complexes
    Djoko, Karrera Y.
    Donnelly, Paul S.
    McEwan, Alastair G.
    METALLOMICS, 2014, 6 (12) : 2250 - 2259
  • [28] STRUCTURE OF BIS(2-FURALDEHYDE THIOSEMICARBAZONATO)NICKEL(II)
    PURANIK, VG
    TAVALE, SS
    ROW, TNG
    UMAPATHY, P
    BUDHKAR, AP
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 2303 - 2304
  • [29] Gold is smaller than silver, crystal structures of [bis(trimesitylphosphine)gold(I)] and [bis(trimesitylphosphine)silver(I)] tetrafluoroborate
    Bayler, A
    Schier, A
    Bowmaker, GA
    Schmidbaur, H
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) : 7006 - 7007
  • [30] CRYSTAL-STRUCTURE OF BIS-(THIOPHENE-2-CARBOXALDEHYDE-4-PHENYL-THIOSEMICARBAZONATO)-PALLADIUM(II)
    SURESH, CG
    DESHPANDE, A
    TAVALE, SS
    UMAPATHY, P
    JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1991, 21 (04): : 485 - 487
12345