Dehydrogenative Diels-Alder Reaction

被引：41
|
作者：
Ozawa, Takuya [1 ]
Kurahashi, Takuya [1 ]
Matsubara, Seijiro [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan
来源：
ORGANIC LETTERS | 2011年 / 13卷 / 19期
关键词：
NATURAL-PRODUCT SYNTHESIS; CYCLOADDITION; ACCELERATION; DIENOPHILES; COMPLEXES; STRATEGY; WATER;
D O I：
10.1021/ol202283d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The dehydrogenative cycloaddition of dieneynes, which possess a diene in the form of a styrene moiety and a dienophile in the form of an alkyne moiety, produces naphthalene derivatives when heated. It was found that a key requirement of this process is the presence of a silyl group attached to the alkyne moiety, which forces a dehydrogenation reaction to occur.
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页码：5390 / 5393
页数：4
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