Dehydrogenative Diels-Alder Reaction

被引：41

作者：

Ozawa, Takuya ^{[1
]}

Kurahashi, Takuya ^{[1
]}

Matsubara, Seijiro ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6158510, Japan

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 19期

关键词：

NATURAL-PRODUCT SYNTHESIS; CYCLOADDITION; ACCELERATION; DIENOPHILES; COMPLEXES; STRATEGY; WATER;

D O I：

10.1021/ol202283d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dehydrogenative cycloaddition of dieneynes, which possess a diene in the form of a styrene moiety and a dienophile in the form of an alkyne moiety, produces naphthalene derivatives when heated. It was found that a key requirement of this process is the presence of a silyl group attached to the alkyne moiety, which forces a dehydrogenation reaction to occur.

引用

页码：5390 / 5393

页数：4

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