A two-dimensional coordination polymer, μ-1,3-benzenedicarboxylato-μ-ethylenediamine-zinc(II) trihydrate

被引:5
|
作者
Jiang, YQ [1 ]
Xie, ZX
Ng, SW
机构
[1] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China
[2] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China
[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
关键词
D O I
10.1107/S1600536803020579
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A two-dimensional zinc(II) coordination polymer, {[Zn(C8H4O4)(C2H8N2)].3H(2)O}(n), has been constructed from zinc(II), 1,3-benzenedicarboxylic acid and ethylenediamine. Within the polymer, each Zn atom is coordinated by two monodentate 1,3-benzenedicarboxylate ligands and two ethylenediamine ligands which define a distorted tetrahedral geometry. The two-dimensional network is further held together by pi-pi stacking interactions and hydrogen-bonding interactions, giving two types of extended one-dimensional channels along the a axis with dimensions of 10.207 (1) x 7.286 (1) Angstrom and 10.207 (1) x 6.240 (1) Angstrom.
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页码:M947 / M949
页数:3
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