A novel two-dimensional chiral coordination polymer:: Bis(S-(-)-lactate) zinc(II)

被引:36
|
作者
Chen, ZF [1 ]
Zhang, J [1 ]
Xiong, RG [1 ]
You, XZ [1 ]
机构
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
基金
中国国家自然科学基金;
关键词
crystal structure; zinc(II) lactate; chiral coordination polymer; hydrothermal synthesis;
D O I
10.1016/S1387-7003(00)00102-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and X-ray characterization of a, novel chiral two-dimensional condensed metal-organic coordination polymer, bis(S(-)-lactate)zinc(II) (1), are reported. Its crystal structure determination shows that a chiral cavity with approximate dimensions of 5.4 X 5.4 Angstrom(2) is present. Crystallographic data for 1, C6H10O6Zn, monoclinic P2(1), a = 7.4440(15), b = 7.4550(15), c = 7.4550(15) Angstrom, beta = 95.73(3)degrees, V= 429.48(15) Angstrom(3), R, = 0.0272, wR(2), = 0.0751. (C) 2000 Elsevier :Science S.A. All rights reserved.
引用
收藏
页码:493 / 496
页数:4
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