[Ni(C10H8N2)3]2[V4O12].11H2O

被引：28
|
作者：
Yang, GY [1 ]
Gao, DW
Chen, Y
Xu, JQ
Zeng, QX
Sun, HR
Pei, ZW
Su, Q
Xing, Y
Ling, YH
Jia, HQ
机构：
[1] Jilin Univ, Dept Chem, Changchun 130023, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270197018751
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystal structure of the title compound, bis[tris(2,2'-bipyridyl-N,N')nickel(II)] cyclo-tetravanadate undecahydrate, contains a centrosymmetric [V4O12](4-) anion, which has an eight-membered ring structure formed by four VO4 tetrahedra sharing vertices, and two complex cations containing octahedrally-coordinated Ni-II ions. The anion and coordinated Ni-II ions are isolated and make up anion and cation layers, respectively. The Ni-N distances range from 2.077(3) to 2.112(2)Angstrom and the V-O distances range from 1.621(2) to 1.803(2)Angstrom.
引用
收藏
页码：616 / 618
页数：3
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