Highly Regio- and Stereoselective Three-Component Nickel-Catalyzed syn-Hydrocarboxylation of Alkynes with Diethyl Zinc and Carbon Dioxide

被引：184

作者：

Li, Suhua ^{[1
]}

Yuan, Weiming ^{[2
]}

Ma, Shengming ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[2] E China Normal Univ, Dept Chem, Shanghai Key Lab Green Chem & Chem Proc, Shanghai 200062, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 11期

基金：

中国国家自然科学基金;

关键词：

alkynes; carbon dioxide; hydrocarboxylation; inorganic fluoride; nickel; NICKEL(0)-MEDIATED SEQUENTIAL ADDITION; TYROSINE KINASE INHIBITORS; METHYLENE-GAMMA-LACTAMS; UNSATURATED-HYDROCARBONS; ARYLATIVE CARBOXYLATION; ALKENYLBORONIC ESTERS; CYTOTOXIC EVALUATION; ORGANOZINC REAGENTS; ALLYL STANNANES; CO2;

D O I：

10.1002/anie.201007128

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrocarboxylation of alkynes: The first example of nickel-catalyzed hydrozincation of alkynes that form stereodefined hydrocarboxylation products is presented (see scheme; cod=cycloocta-1,5-diene). This catalytic system is efficient for the activation of CO2 and the three-component reaction produces products that could be converted into important oxindole or γ-butyrolactam derivatives. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2578 / 2582

页数：5

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