catena-Poly[[chloridocopper(II)]bis(μ-3,3′,5,5′-tetramethyl-4,4′-methylenedipyrazole)[chloridocopper(II)]-di-μ-chlorido]

被引：1
|
作者：
Wang, Zhi-Min [1 ]
机构：
[1] Zhejiang Shuren Univ, Coll Biol & Environm Engn, Hangzhou 310015, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808006909
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu2Cl4(C11H16N4)](n), the Cu atom is coordinated by two N atoms of two 3,3',5,5'-tetramethyl-4,4'-methylenedipyrazole (H(2)mbdpz) ligands, two bridging Cl atoms and one terminal Cl atom, forming a square-pyramidal geometry. The bridging Cl atoms and the bridging H2mbdpz ligands connect the Cu atoms to build up an extended one-dimensional chain. The chains are further connected through N-H center dot center dot center dot Cl hydrogen bonds to build up a two-dimensional layer in the (011) plane. An inversion centre lies between every pair of adjacent Cu atoms.
引用
收藏
页码：M561 / U444
页数：8
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