catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine]

被引:1
|
作者
Ling, Chun-Sheng [2 ]
Han, Qiu-Xia [1 ]
机构
[1] Henan Univ, Basic Expt Teaching Ctr, Kaifeng 475004, Peoples R China
[2] Henan Univ, Pharmaceut Coll, Kaifeng 475004, Peoples R China
关键词
D O I
10.1107/S1600536808032558
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Co(C9H5O6)(2)(C10H8N2)](n), the asymmetric unit consists of one Co2+ ion with site symmetry 2, one mono-deprotonated 1,3,5-benzenetricarboxylic acid anion and one-half of a 4,4'-bipyridine (4,4'-bipy) molecule, in which two N and two C atoms have site symmetry 2. In the crystal structure, the Co2+ centre is coordinated by four O atoms from two bidentate carboxylate groups of two anions and two N atoms of two 4,4'-bipy molecules, resulting in infinite chains propagating in [010]. The cobalt coordination is distorted trans-CoO4N2 octahedral and interchain O-H center dot center dot center dot O hydrogen bonds complete the structure.
引用
收藏
页码:M1400 / U477
页数:11
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