Pd2(dba)3/Xantphos-catalyzed cross-coupling of thiols and aryl bromides/triflates

被引:182
|
作者
Mispelaere-Canivet, C
Spindler, JF
Perrio, S
Beslin, P
机构
[1] Univ Caen, ENSICAen, Lab Chim Mol & Thioorgan, CNRS UMR 6507, F-14050 Caen, France
[2] Ctr Rech Lyon, RHODIA, POP ISV, F-69192 St Fons, France
关键词
palladium catalysis; thiol cross-coupling;
D O I
10.1016/j.tet.2005.03.078
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The cross-coupling of aliphatic and aromatic thiols and aryl bromides/triflates mediated by a Pd-2(dba)(3)/Xantphos catalytic system in refluxing xylene (140 degrees C) affords the corresponding aryl thioethers in good to excellent yields. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5253 / 5259
页数:7
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