Glycosylation Reaction of Thioglycosides by Using Hypervalent Iodine(III) Reagent as an Excellent Promoter

被引：11
|
作者：
Kajimoto, Tetsuya [1 ]
Morimoto, Koji [1 ]
Ogawa, Ryosuke [2 ]
Dohi, Toshifumi [2 ]
Kita, Yasuyuki [1 ,2 ]
机构：
[1] Ritsumeikan Univ, Res Org Sci & Technol, 1-1-1 Nojihigashi, Kusatsu, Shiga 5258577, Japan
[2] Ritsumeikan Univ, Coll Pharmaceut Sci, 1-1-1 Nojihigashi, Kusatsu, Shiga 5258577, Japan
来源：
CHEMICAL & PHARMACEUTICAL BULLETIN | 2016年 / 64卷 / 07期
基金：
日本学术振兴会;
关键词：
glycosylation; hypervalent iodine reagent; thioglycoside; ODORLESS BENZENETHIOLS; MEDIATED ACTIVATION; POLYVALENT IODINE; ORGANIC-SYNTHESIS; GLYCOSIDES; DONORS; CHEMISTRY; OLIGOSACCHARIDE; PRODUCT; LINKAGE;
D O I：
10.1248/cpb.c16-00203
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Thioglycosides are available donors in glycosylation due to the stability of the anomeric C-S bond under general reaction conditions of protection and deprotection, and offer orthogonality in their activation. We report now that the hypervalent iodine effectively induced glycosylation reaction of thioglycosides with various alcohols. This method features a high efficiency, completion in a short time, and proceeding under very mild conditions.
引用
收藏
页码：838 / 844
页数：7
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