Highly Efficient, Organocatalytic Aerobic Alcohol Oxidation

被引：170

作者：

Shibuya, Masatoshi ^{[1
]}

Osada, Yuji ^{[1
]}

Sasano, Yusuke ^{[1
]}

Tomizawa, Masaki ^{[1
]}

Iwabuchi, Yoshiharu ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 17期

基金：

日本学术振兴会;

关键词：

TRANSITION-METAL-FREE; NITROXYL RADICALS; CATALYTIC OXIDATIONS; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; 2-PHASE CONDITIONS; MILD CONDITIONS; NUCLEOTIDES; NUCLEOSIDES; KETONES;

D O I：

10.1021/ja110940c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5- Fluoro-2-azaadamantane N-oxyl (5-FAZADO) realizes a simple, organocatalytic aerobic alcohol oxidation system that has a wide scope under mild conditions at ambient pressure and temperature and is weakly acidic and halogen- and transition-metal-free. The oxoammonium nitrate (5-F-AZADO(+)NO(3)(-)) works as a bifunctional catalyst of 5-F-AZADO and NO(x) that enables the catalytic aerobic oxidation of alcohols by itself (a metal-salt-free system).

引用

页码：6497 / 6500

页数：4

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