Highly Efficient, Organocatalytic Aerobic Alcohol Oxidation

被引：170

作者：

Shibuya, Masatoshi ^{[1
]}

Osada, Yuji ^{[1
]}

Sasano, Yusuke ^{[1
]}

Tomizawa, Masaki ^{[1
]}

Iwabuchi, Yoshiharu ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Dept Organ Chem, Sendai, Miyagi 9808578, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 17期

基金：

日本学术振兴会;

关键词：

TRANSITION-METAL-FREE; NITROXYL RADICALS; CATALYTIC OXIDATIONS; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; 2-PHASE CONDITIONS; MILD CONDITIONS; NUCLEOTIDES; NUCLEOSIDES; KETONES;

D O I：

10.1021/ja110940c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5- Fluoro-2-azaadamantane N-oxyl (5-FAZADO) realizes a simple, organocatalytic aerobic alcohol oxidation system that has a wide scope under mild conditions at ambient pressure and temperature and is weakly acidic and halogen- and transition-metal-free. The oxoammonium nitrate (5-F-AZADO(+)NO(3)(-)) works as a bifunctional catalyst of 5-F-AZADO and NO(x) that enables the catalytic aerobic oxidation of alcohols by itself (a metal-salt-free system).

引用

页码：6497 / 6500

页数：4

共 50 条

[21] A mild and highly efficient laccase-mediator system for aerobic oxidation of alcohols
Zhu, Chenjie
Zhang, Zhi
Ding, Weiwei
Xie, Jingjing
Chen, Yong
Wu, Jinglan
Chen, Xiaochun
Ying, Hanjie
GREEN CHEMISTRY, 2014, 16 (03) : 1131 - 1138
[22] Theoretical Studies on Muti-Hydroxyimides as Highly Efficient Catalysts for Aerobic Oxidation
Chen, Kexian
Jia, Lu
Dao, Rina
Yao, Jia
Wang, Congmin
Chen, Zhirong
Li, Haoran
CHEMPHYSCHEM, 2013, 14 (01) : 179 - 184
[23] Highly selective aerobic oxidation of alcohol catalyzed by a Gold(I) complex with an anionic ligand
Guan, BT
Xing, D
Cai, GX
Wan, XB
Yu, N
Fang, Z
Yang, LP
Shi, ZJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (51) : 18004 - 18005
[24] A Facile Preparation of Highly Active Au/MgO Catalysts for Aerobic Oxidation of Benzyl Alcohol
Zhen Wang
Chunli Xu
Hanfei Wang
Catalysis Letters, 2014, 144 : 1919 - 1929
[25] A Facile Preparation of Highly Active Au/MgO Catalysts for Aerobic Oxidation of Benzyl Alcohol
Wang, Zhen
Xu, Chunli
Wang, Hanfei
CATALYSIS LETTERS, 2014, 144 (11) : 1919 - 1929
[26] Highly selective aerobic oxidation of alcohol catalyzed by a Gold(I) complex with an anionic ligand
Guan, Bingtao
Xing, Dong
Cai, Guixing
Wan, Xiaobin
Yu, Nan
Fang, Zhao
Yang, Liping
Shi, Zhangjie
Journal of the American Chemical Society, 2005, 127 (51): : 18004 - 18005
[27] Aerobic alcohol oxidation: Ready for primetime?
Stahl, Shannon S.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[28] Highly efficient Ni-Co oxide nanoparticles on nitrogen-doped FDU-15 for aerobic benzyl alcohol oxidation
Fu, Xiaoran
Wu, Shujie
Li, Zhifang
Yang, Xiaoyuan
Wang, Xiufang
Peng, Ling
Hu, Jing
Huo, Qisheng
Guan, Jingqi
Kan, Qiubin
RSC ADVANCES, 2016, 6 (62) : S7507 - S7513
[29] Nitroxyl radical TEMPO: An organocatalyst for highly efficient and selective oxidation of alcohol
Yang Guanyu
Guo Yanchun
Wu Guanghui
Zheng Liwen
Song Maoping
PROGRESS IN CHEMISTRY, 2007, 19 (11) : 1727 - 1735
[30] Organocatalytic Aerobic Oxidation of α-Fluoroalkyl Alcohols to Fluoroalkyl Ketones at Room Temperature
Kadoh, Yoichi
Tashiro, Masayuki
Oisaki, Kounosuke
Kanai, Motomu
ADVANCED SYNTHESIS & CATALYSIS, 2015, 357 (10) : 2193 - 2198

← 1 2 3 4 5 →