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A MICROPOROUS METAL-ORGANIC FRAMEWORK WITH OPEN METAL SITES FOR SELECTIVE SENSING Fe3+, CrO42- AND NITROBENZENE
被引:5
|作者:
Wang, Fu-Min
[1
]
Wang, Rui
[2
,3
]
Han, Yao-Yao
[2
,3
]
Li, Sa-Ying
[1
]
Man, Jian-Hui
[2
,3
]
He, Yong-Xiang
[2
,3
]
Li, Bao-Hong
[2
,3
]
机构:
[1] Shaanxi Xueqian Normal Univ, Dept Chem & Chem Engn, Xian, Shaanxi, Peoples R China
[2] Guangdong Med Univ, Key Lab Res & Dev New Med Mat, Dongguan 523808, Peoples R China
[3] Guangdong Med Univ, Sch Pharm, Dongguan 523808, Peoples R China
关键词:
Metal-organic framework;
Luminescence quenching;
Iron(III);
Chromate;
Nitrobenzene;
LUMINESCENT;
RECOGNITION;
ZN(II);
CU(II);
IONS;
MOF;
COMPLEXES;
EMISSION;
NI(II);
SENSOR;
D O I:
10.4314/bcse.v31i2.10
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A 3D network with the (4(2).6.8(3)) topology of metal- organic framework possessing an open 1D channel was synthesized by rigid and planar tetracarboxylic acid 5,5'-(1H-2,3,5-triazole-1,4-diyl) diisophthalic acid (H4L). The luminescent properties of 1 shows highly sensitive response to nitrobenzene, Fe3+ and CrO42- through luminescence quenching effects, making it a promising luminescent sensor for nitro aromatic compounds, Fe3+ and CrO42-.
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页码:291 / 297
页数:7
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