Luminescent Anionic Metal-Organic Framework with Potential Nitrobenzene Sensing

被引：130

作者：

He, Yuan-Chun ^{[1
]}

Zhang, Hong-Mei ^{[1
]}

Liu, Ying-Ying ^{[1
]}

Zhai, Qiu-Yi ^{[1
]}

Shen, Qiu-Tong ^{[1
]}

Song, Shu-Yan ^{[2
]}

Ma, Jian-Fang ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2014年 / 14卷 / 07期

基金：

中国国家自然科学基金;

关键词：

PHOTOLUMINESCENCE; ADSORPTION; LIGAND; SENSOR; SERIES; MOF;

D O I：

10.1021/cg5004353

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvothermal reaction of multidentate organic ligand, 5,5',5 '',5 ''',5],5]'-[1,2,3,4,5,6-phenylhexamethoxyl]-hexaisophthalic acid (H12L), with Cd(NO3)center dot 4H(2)O produced an anionic 3D metal-organic framework [(CH3)(2)NH2](4)[Cd-3(H2L)] (1), which features a novel cage-to-cage connection. Interestingly, the 1D channel, which is stacked by cages, is divided into uniform segments by molecular-scale bricks. The luminescent properties of compound 1 have been explored, which shows that 1 is a potential luminescent sensory material for nitrobenzene.

引用

页码：3174 / 3178

页数：5

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