Improving the Capacity of Sodium Ion Battery Using a Virus-Templated Nanostructured Composite Cathode

被引:72
|
作者
Moradi, Maryam [1 ,2 ]
Li, Zheng [1 ]
Qi, Jifa [1 ]
Xing, Wenting [1 ]
Xiang, Kai [1 ]
Chiang, Yet-Ming [1 ]
Belcher, Angela M. [1 ,2 ,3 ]
机构
[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA
[2] MIT, David H Koch Inst Integrat Canc Res, Cambridge, MA 02139 USA
[3] MIT, Dept Biol Engn, Cambridge, MA 02139 USA
关键词
Sodium ion battery; amorphous FePO4; biotemplated active material; SWCNT; high-power rechargeable battery; ENERGY-STORAGE; LITHIUM; NANOWIRES; STABILITY; OLIVINES; LI;
D O I
10.1021/nl504676v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work we investigated an energy-efficient biotemplated route to synthesize nanostructured FePO4 for sodium-based batteries. Self-assembled M13 viruses and single wall carbon nanotubes (SWCNTs) have been used as a template to grow amorphous FePO4 nanoparticles at room temperature (the active composite is denoted as Bio-FePO4-CNT) to enhance the electronic conductivity of the active material. Preliminary tests demonstrate a discharge capacity as high as 166 mAh/g at C/10 rate, corresponding to composition Na0.9FePO4, which along with higher C-rate tests show this material to have the highest capacity and power performance reported for amorphous FePO4 electrodes to date.
引用
收藏
页码:2917 / 2921
页数:5
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